Isotropic to nematic transition of aerosil-disordered liquid crystals.

نویسندگان

  • M Caggioni
  • A Roshi
  • S Barjami
  • F Mantegazza
  • G S Iannacchione
  • T Bellini
چکیده

We present a high-resolution study of the isotropic to nematic phase transition of a low birefringence liquid-crystal compound incorporating an aerosil gel. Calorimetry, light scattering, and microscopy data coherently combine to allow for an accurate determination of the temperature dependence of the onset of the nematic state. The nematic order develops on cooling through two distinct processes while the nematic correlation length mildly decreases. We understand the doubling of the phase transition as due to a crossover from a random-dilution regime, where the silica gel couples to the scalar part of the nematic order parameter, to a low-T random-field regime, where the coupling induces distortions in the director field.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Investigation into the temperature dependence of isotropic- nematic phase transition of Gay- Berne liquid crystals

Density functional approach was used to study the isotropic- nematic (I-N) transition and calculate the values of freezing parameters of the Gay- Berne liquid crystal model. New direct and pair correlation functions of a molecular fluid with Gay- Berne pair potential were used. These new functions were used in density functional theory as input to calculate the isotropic- nematic transition den...

متن کامل

Evolution of the isotropic-to-nematic phase transition in octyloxycyanobiphenyl+aerosil dispersions.

High-resolution ac calorimetry has been carried out on dispersions of aerosils in the liquid crystal octyloxycyanobiphenyl (8OCB) as a function of aerosil concentration and temperature spanning the crystal to isotropic phases. The liquid crystal 8OCB is elastically stiffer than the previously well studied octylcyanobiphenyl (8CB)+aerosil system and so general quenched random-disorder effects an...

متن کامل

ESR studies of order and dynamics in a nematic liquid crystal containing a dispersed hydrophobic aerosil

We have studied a system composed of an hydrophobic aerosil (R812) dispersed in the liquid crystal 4-n-octyl-4’-cyanobiphenyl (8CB) using the spin probe ESR technique and, in particular, we have determined, for different aerosil concentrations, the temperature dependence of the orientational order parameter 〈P2〉 and the rotational diffusion coefficient D⊥ of the probe 5-doxyl stearic acid in th...

متن کامل

Effect of aerosil gels on de Gennes nematic-smectic coupling.

There is a well-known de Gennes coupling between the scalar nematic order parameter S and the smectic density-wave amplitude /Psi/, which causes the nematic-smectic-A phase transition to cross over from second order to first order via a tricritical point. This sort of crossover is observed for numerous liquid crystals (LCs) with small to moderate nematic ranges. Recent studies of LC+aerosil sys...

متن کامل

Slow Molecular Processes in a Liquid Crystal Embedded in Aerosil Matrix: Nuclear Magnetic Relaxometric Study

Frequency dispersion studies on proton spin-lattice relaxation rates of a liquid crysal (4’-octyloxy-4-cyanobiphenyl) embedded in Aerosil matrix show significant increase at low frequencies (sub-MHz regime) relative to the bulk sample, and are interpreted as primarily due to slow reorientations near the surface ordered layers mediated by translation displacements. The computed exponent in the p...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 93 12  شماره 

صفحات  -

تاریخ انتشار 2004